Sov. electrochemistry 25 No1 (1989) 25-32

Concerning the theory of latent limiting diffusion currents

A. V. Sokirko and Yu. I. Kharkats

The paper theoretically examines parallel electrode processes occurring under conditions when the product of one of them is involved in a homogeneous reaction with a reactant of the other. As a result the limiting current of the second reaction depends on the current of the first, and an effect is seen which was called a "latent limiting current" by Kemula and Grabowski. The analytical and numerical calculations performed cover a wide range of parameters of the problem, and include the results of Kemula and Grabowski as a particular case for the limit of an infinitely high rate constant of the homogeneous reaction.

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